S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II

By Reimund Jotter, Norbert Baumann, Hans-Jurgen Fachmann, et al.

The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida- tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or- ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi- tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one- coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 ]) ( S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR, R = organyl). Only the reac- 2 tions of S=N=S]+ AsF5, among the known S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.

• Format: Paperback
• Language: English
• ISBN: 3662063530
• ISBN13: 9783662063538
• Release Date: October 2013
• Publisher: Springer
• Length: 324 Pages
• Weight: 1.35 lbs.
• Dimensions: 0.7" x 7.0" x 10.0"